| 二茂铁甲酰丙酮缩氨基硫脲金属配合物研究 |
| STUDIESOF METAL COMPLEXESOF FERROCENOYLACETONE THIOSEMICARBAZONE |
|
| 摘要: 将二茂铁甲酰丙酮与硫代氨基脲在水-乙醇介质中进行缩合反应,得金属有机多齿配体C5H5FeC5H4COCH2C(CH3)=NNHCSNH2(简记作FcTS),该配体分别与d-过渡金属[Cu(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、Mn(Ⅱ)]、B族金属[Zn(Ⅱ)、Cd(Ⅱ)]及主族金属[Pb(Ⅱ)]乙酸盐反应,合成了分子式为(FcTS)2M(CH3COO)2的7个新型配合物。经元素分析、IR、UV-Vis,1HHMR、摩尔电导及固体电导的测定对配合物组成、结构、波谱性质和导电性能进行了研究。 |
| 关键词: 二茂铁衍生物 金属有机配体 配合物 合成与性质 |
| 基金项目: 国家自然科学基金资助项目 |
| Abstract: An organometallic ligand C5H5FeC5H4COCH2C(CH3)=NNHCSNH2(FcTS) was obtained by the condensation of ferrocenoylacetone and thiosemicarbazide in ethanolaqueous media and seven complexes of d-transition metals(Mn(Ⅱ),Co(Ⅱ),Ni(Ⅱ),Cu(Ⅱ)), B group metals(Zn(Ⅱ),Cd(Ⅱ)),and main group metal(Pb(Ⅱ)) were prepared by the reaction of FcTS and relevant metal acetate. The chemical constitutions,structures,spectrum properties and conductances of the complexes were discussed by microanalyses,IR,UVV is,1H NMR and determination of the molar conductivities and the solid conductivities. |
| Keywords: ferrocene derivative organometallic ligand complex synthesis and property |
| 投稿时间：1994-12-05 |
| 摘要点击次数: 1275 |
| 全文下载次数: 1587 |
| 胡培植,季立才,王亚夫,张伦.二茂铁甲酰丙酮缩氨基硫脲金属配合物研究[J].无机化学学报,1996,12(1):12-17. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
