| 铕与PMBP配合物晶体结构和电子结构的研究 |
| STUDY ON CRYSTAL AND ELECTRONIC STRUCTURE OF EUROPIUM(Ⅲ) WITH 1-PHENYL-3-METHYL-4-BENZOYL-PYROZOLONE-5(HPMBP) |
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| 摘要: |
| 关键词: 铕 HPM BP 晶体结构 电子结构 |
| 基金项目: |
| Abstract: The title complex Eu(PMBP)3·2H2O has been synthesized. The crystal is monoclinic with space group of P21/n,a=14.9821(1)Å,b=14.75 18(8)Å,c=24.4979(9)Å,β=101.52°. Each europium ion is coordinated by 8 oxygen atoms,contributed by three PMBP and two watermolecules,arranged atthevertices of a square antiprism. The electronicstructure of the complex was calculated using the INDO/ F program.The molecular orbital energy, charge distribution,and Mulliken bond order of the structure and bonding characters of EuL3·2H2O have been discussed. |
| Keywords: europium HPMBP crystal structure electronic structure |
| 投稿时间：1995-05-03 |
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| 潘龙郑,能武,杨灵法,刘海铭,杨耀,杨文娟.铕与PMBP配合物晶体结构和电子结构的研究[J].无机化学学报,1996,12(1):107-110. |
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