| 在DBU存在下酞菁锰配合物的合成及溶剂影响 |
| SYNTHESIS OF MANGANESE PHTHALOCYANINE AND STUDIES OF SOLVENT EFFECT IN THE PRESENCE OF DBU |
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| 摘要: 在强有机碱1,8-二氮杂双环[5,4,0]十一-7烯(简称DBU)存在下,MnCl2与邻二氰基苯在某些二元醇溶剂中可高效合成Mn(Ⅱ)Pc(Pc表示酞菁),同时研究了不同溶剂对合成产物的物种及产率的影响和不同氧化态锰的酞菁配合物在一些醇溶剂中的互变现象。 |
| 关键词: 酞菁锰配合物 合成 溶剂作用 DBU |
| 基金项目: |
| Abstract: In the presence of a strong organic base 1,8-diazab icyclo[5, 4, 0]undec-7-ene (DBU),m anganese(Ⅱ)phthalocyaninewas synthesized effectively by heating phthaloni-trite with manganese chloride in some diols The effectwas studied on the yield and pieces of synthesis products in different solvents Lability of different valence satate manganese phthalocyaninewas also discussed in some alcohol solvents |
| Keywords: manganese phthalocyanine synthesis solvent effect DBU |
| 投稿时间：1995-07-24 |
| 摘要点击次数: 1854 |
| 全文下载次数: 1625 |
| 聂静涛,段武彪,杨素苓,陈耐生.在DBU存在下酞菁锰配合物的合成及溶剂影响[J].无机化学学报,1996,12(3):246-250. |
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