| 萃取法研究混配配合物中配体间的芳环堆积作用Ⅲ．Cu2+-phen-PCA-体系 |
| STUD IESON THE AROMATIC RING STACKING INTERL IGAND INTERACTDNS BY EXTRACTDN M ETHOD Ⅲ.Cu2+-phen-PCA- SYSTEM |
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| 摘要: 用萃取法研究Cu2+-phen-PCA-体系中配体间的芳环堆积作用(phen=1,10-邻菲罗啉,PCA-=苯甲酸根(Bz-)、α-苯乙酸根(PAc-)、β-苯丙酸根(PPr-)和γ-苯丁酸根(PBu-),结果表明,配合物中芳环堆积作用依赖于PCA-中苯环与羧酸根间碳链的长度,其顺序为：Bz----。 |
| 关键词: 芳环堆积作用 Cu2+-phen-PCA-体系 萃取 |
| 基金项目: 国家和浙江省自然科学基金 |
| Abstract: The stacking interactions of aromatic rings in the Cu2+-phen-PCA- system,where phen=1,10-phenanthroline and PCA=benzoate(Bz),α-phenylacetate(PAC),β-phenylacetate(PPr) and γ-phenylacetate(Pbu) have been studied by extraction method in perchloric acid medium.The content of the stacked isomers in the order: Bz----.The complexes composition have been determined by the slope method, IR spetra and elemental analyses too. |
| Keywords: aromatic rhgs hteraction copper-1,10-phenanthroliie-phenylcarboxylic acid extraction |
| 投稿时间：1995-09-04 |
| 摘要点击次数: 1257 |
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| 林秋月,龚钰秋,冯旭文.萃取法研究混配配合物中配体间的芳环堆积作用Ⅲ．Cu2+-phen-PCA-体系[J].无机化学学报,1996,12(3):322-325. |
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