| 单磺化酞菁镓在水、微乳液中的解聚反应动力学研究 |
| STUDY ON THE AGGREGATION AND THE KINETICS OF AGGREGATION REACTION OF THE MONO-SULFOPHTHALOCYANINOATO GALLIUM IN THE AQUEOUS SOLUTION AND MICROEMULSION SYSTEM |
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| 摘要: 本文研究了单磺化酞菁镓(SPcGa)在水、微乳液(TritonX-100-壬烷-正戊醇-水)中的二聚现象和解聚反应动力学,测定了二聚平衡常数KD和解聚速率常数k.结果表明：SPcGa的解聚反应速率与SPcGa的单体浓度CM和双体浓度CD的关系为：V=k1CD-k2CM2. |
| 关键词: 酞菁 镓 微乳液 聚合 动力学 |
| 基金项目: 江苏省教委自然科学基金资助项目 |
| Abstract: The dimerization and kinetics of aggregation of mono-sulfophthal aninoato gallium (SPcGa) was studied in the aqueous solution and microemulsion system(Triton X-100-Pen-tanol-Monane-Water) by spectrophotometry.The dimerization constant(kDn) and the rate constant(k) of aggregation reaction of SPcGa were calculated. It shows that the rate of ag-gregation reaction of SPcGa can be expressed as follows:V=k1CD-k2CM2. Where Cm and CD are concentrations of monomer and dimer of SPcGa respectively. It also shows that kD of SPcGa is decreased in the microemulsion system as compared with that in aqueous solution. |
| Keywords: phthalocyanine gallium microemulsion aggregation kinetics |
| 投稿时间：1995-09-19 |
| 摘要点击次数: 1098 |
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| 袁诗海,孙美丽,吴星.单磺化酞菁镓在水、微乳液中的解聚反应动力学研究[J].无机化学学报,1996,12(3):329-332. |
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