| 甲基苯基苄基膦的拆分 |
| RESOLUTION OF MePhBzP |
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| 摘要: 本文报道了用R-μ-二氯-二(N,N-二甲基-α-萘乙胺)合二钯(Ⅱ)为拆分试剂,拆分标题化合物的过程和结果。S-甲基苯基苄基膦的[α]D25=+110.3°(C=2.82%,C6H5CH3),比文献报道值为高。并用31PNMR信号对拆分纯度进行了讨论. |
| 关键词: 甲基苯基苄基膦 非对映异构体 拆分 |
| 基金项目: |
| Abstract: The title compound was resolved by using the resolving agent R-Di-μ-chloro-bis[dimethyl(1-ethyl-α-naphthyl)aminat o]dipalladium(Ⅱ).[α]D25=+110.3°(C=2.82%,C6H5CH3).31PNMR showed the s-MePhBzP was optically pure. |
| Keywords: MePhBzP diastereoisomer resolution |
| 投稿时间：1995-10-18 |
| 摘要点击次数: 1400 |
| 全文下载次数: 1578 |
| 宋玉民.甲基苯基苄基膦的拆分[J].无机化学学报,1996,12(3):345-347. |
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