| 邻苯二酚衍生物与希土元素的配位反应Ⅱ．铈(Ⅳ)配合物显现颜色机理的探讨 |
| COORDINATION OF RARE EARTH ELEMENTS WITH DERIVATIVES OF CATECHOL Ⅱ. STUDY ON MECHANISM OF COLOURING OF COORDINATION COMPOUNDS OF Ce(1V) WITH CATECHOL DERIVATIVES |
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| 摘要: 用实验与量化计算对邻苯二酚类衍生物与铈(Ⅳ)生成的配合物显现颜色的机理进行了探讨,认为是由配体上大π键电子向中心金属离子跃迁所产生的L→M荷移所致. |
| 关键词: 铈 邻苯二酚衍生物 机理 |
| 基金项目: |
| Abstract: The mechanism of colouring of coordination compounds of Ce(1V) with catechol derivatives has been put forward and investigated. The mechanism has been explained by some experiments and calculation of quantum chemistry. |
| Keywords: cerium catechol derivative mechanism |
| 投稿时间：1995-09-27 |
| 摘要点击次数: 1307 |
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| 邓建成,钟超凡,赵鸿斌,童珏.邻苯二酚衍生物与希土元素的配位反应Ⅱ．铈(Ⅳ)配合物显现颜色机理的探讨[J].无机化学学报,1996,12(4):362-367. |
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