| 铜(Ⅰ)配合物[Cu(C8H4O2F3S)(PPh3)2]合成、性质、晶体结构及反应机理的探讨 |
| SYNTHESIS, CHARACTERIZATION AND CRYSTAL STRUCTURE OF COPPER (Ⅰ) [Cu(C8H4O2F3S)(PPh3)2] |
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| 摘要: |
| 关键词: 铜粉 三苯基膦 晶体结构 |
| 基金项目: 国家自然科学基金 |
| Abstract: Reaction of copper powder with 2-thenoyltrifluoroacetone and PPh3 yielded the complex [Cu(C8H4O2F3S)(PPh3)2], which have been characterized by elemental analysis and IR spectra. The crystal is monoclinic, space group P21/n , a=1.0584(1), b=1.6738(1), c=2.2728(9) nm; β =94.22(2); V =4.0152 nm 3; Z=4; Dc=1.299 g·cm-3; R=0.048, RW=0.054. Copper (Ⅰ) ion is coordinated by two O and two P atoms forming distorted tetrahedron. |
| Keywords: copper powder PPh3 crystal structure |
| 投稿时间：1995-12-26 |
| 摘要点击次数: 1792 |
| 全文下载次数: 1945 |
| 王冬梅,杨瑞娜,侯益民,金斗满.铜(Ⅰ)配合物[Cu(C8H4O2F3S)(PPh3)2]合成、性质、晶体结构及反应机理的探讨[J].无机化学学报,1996,12(4):440-442. |
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