几种硅藻土的表面电化学性质的研究
A STUDY ON SURFACE ELECTROCHEMICAL PROPERTIES OF SEVERAL DIATOMITES
作者单位
杨宇翔 同济大学化学系 上海 200092 
吴介达 同济大学化学系 上海 200092 
黄忠良 同济大学化学系 上海 200092 
陈荣三 南京大学配位化学研究所 配位化学国家重点实验室 南京 210093 
戴安邦 南京大学配位化学研究所 配位化学国家重点实验室 南京 210093 
摘要: 研究了浙江、吉林等地几种国内硅藻土的表面ζ电位与pH的关系曲线,测定了它们的等电点。其中吉林土等电点最小,表面酸强度最大。在所试条件下,浙江土和吉林土随着焙烧温度升高,等电点值增大,尿激酶吸附量随酸浓度增大而逐渐减小。而浙江土和酸洗浙江土在400℃时等电点最小,酸浓度最大,吉林土在400℃时比表面最大,三者对尿激酶吸附量也最大。酸洗后,浙江土等电点值增大,酸浓度则减小,尿激酶吸附量也相应减小。
关键词: 等电点 酸强度 硅藻土 尿激酶
基金项目: 
Abstract: In this paper, the curves of surface ζ potential versus pH for Zhejiang, Jilin and other several local diatomites were studied, and their isoelectrical point(IEP) values were determined. Among them, the acid strength of Jilin diatomite surface attained maximum value and IEP minimum, their acid strengths were concerned with the structure of diatom frustules. Under the experiment conditions, IEP value of Zhejiang and Jilin diatomite increased with roasting temperature, so that the capacity of adsorption of urokinase increased gradually according to the surface acid strength. When diatomite roasted at 400℃ their acid strength attained maximum value and IEP minimum, only did specific surface of Jilin diatomite attained maximum value, so their capacity of adsorption of urokinase attained maximum value, after diatomite was washed with acid, its IEP value increased, and acid strength decreased, the capacity of adsorption of urokinase also decreased accordingly.
Keywords: isoelectrical point acid strength diatomite urokinase
 
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杨宇翔,吴介达,黄忠良,陈荣三,戴安邦.几种硅藻土的表面电化学性质的研究[J].无机化学学报,1997,13(1):11-15.
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