| (Me4N)［Mo3(μ3-O)(μ-Cl)3(μ-O2CCH2Cl)3Cl3］三核钼簇合物的合成、结构及电化学研究 |
| STUDY ON THE SYNTHESIS， CRYSTAL STRUCTURE AND ELECTROCHEMISTRY OF THE TRINUCLEAR MOLYBDENUM CLUSTER COMPOUND，(Me4N)［Mo3(μ3-O)(μ-Cl)3(μ-O2CCH2Cl)3Cl3］ |
|
| 摘要: 本文测定了三核钼簇合物-(Me4N)［Mo3(μ3-O)(μ-Cl)3(μ-O2CCH2Cl)3Cl3］的晶体结构，该晶体属于正交晶系，空间群P212121，晶胞参数：a=12.6375(9), b=18.894(4), |
| 关键词: 三核钼簇合物 合成 晶体结构 电化学 |
| 基金项目: |
| Abstract: The crystal structure of the title cluster was determined in this paper. It belongs to the orthorhombic system, space group P212121, with crystal cell parameters: a=12.6375(9), b=18.894(4), c=10.733(4)?, Mr=871.15, Z=4, Dc=2.26 g/cm3. The results reveal that it belongs to a discrete ionic compound. Three molybdenum atoms of the cluster form a approximately equilateral triangle with Mo-Mo bond length (av., 2.577?). One (μ3-O)atom is coordinated to the three Mo atoms together, forming a mono-capped cluster skeleton, with Mo-(μ3-O) bond distance (av., 1.980?). The symmetry of the cluster is approximately C3v. The redox potential of the title cluster was measured by the cyclic voltammetry in acetonitrile solvent. |
| Keywords: trinuclear molybdenum cluster synthesis crystal structure electrochemistry |
| |
| 摘要点击次数: 1189 |
| 全文下载次数: 1318 |
| 霍丽华,陈耐生,张汉辉,黄金陵.(Me4N)［Mo3(μ3-O)(μ-Cl)3(μ-O2CCH2Cl)3Cl3］三核钼簇合物的合成、结构及电化学研究[J].无机化学学报,1997,13(2):146-151. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
