| N-对氯苯基氮杂15冠5八钼多酸钠超分子配合物的结构与热分解 |
| CRYSTAL STRUCTURE AND THERMAL DECOMPOSITION OF ［Na(N-(p-ClPh)15C5)(Et2O)］2Na2Mo8O26 |
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| 摘要: 本文对新型超分子配合物［Na(N-(p-ClPh)-15-C-5(Et2O)］2N2Mo8O26进行了X-射线四圆衍射测定，该晶体属单斜晶系，空间群为P21/c,a=1.7803(4), b=1.3674(3), c=1.4610(3)(nm), β=112.33(2)°, |
| 关键词: N-对氯苯基氮杂15冠5 八钼多酸钠阴离子 热分解 |
| 基金项目: |
| Abstract: The crystal structure of supermolecular complex of ［Na(N-(p-ClPh)15C5)(Et2O)］2Na2Mo8O26 were determined by X-ray diffraction with the crystal parameters of a=1.7803(4) nm, b=1.3674(3) nm, c=1.4610(5) nm, β=112.33(2)°, V=3.290(1) nm3, Mr=2021.3, Dc=2.14 g/cm3, μ=1.704 nm-1, F(000)=2079.63, R=0.0256 and RW=0.0295. The thermal decomposition procedure of the title complex were discussed also by thermal decomposition and 1H NMR experiments. |
| Keywords: N-(para-chlorophenyl)aza-15-crown-5 octamolybdate anion thermal decomposition |
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| 鲁晓明,屠淑洁,乔赤兵,刘顺诚.N-对氯苯基氮杂15冠5八钼多酸钠超分子配合物的结构与热分解[J].无机化学学报,1997,13(2):152-158. |
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