希土(Ⅲ)噻吩甲酰三氟丙酮和BipyO2/PhenNO三元配合物的合成和表征
SYNTHESIS AND CHARACTERIZATION OF RARE EARTH(Ⅲ) TERNARY COMPLEXES WITH THENOYLTRIFLUOROACETONATE AND BipyO2 or PhenNO
作者单位
成义祥 浙江大学化学系杭州 310027 
徐端钧 浙江大学化学系杭州 310027 
徐元植 浙江大学化学系杭州 310027 
摘要: 
关键词: 希土 三元配合物 噻吩甲酰三氟丙酮 荧光光谱
基金项目: 
Abstract: The new ternary complexes of RE(TTA)3(BipyO2)·H2O and RE(TTA)3 (PhenNO)(where RE=Sm, Eu, Gd; TTA=thenoyltrifluoroacetonate; BipyO2=2,2′-bipyridine-N,N′-dioxide; PhenNO=1,10-phenanthroline-N-oxide)have been synthesized. The composition and properties of complexes were studied by elemental analysis, UV spectrum, IR spectrum, DTA-TG and fluorescence spectrum. The effect of solvent on fluorescent intensity is discussed.
Keywords: rare earth ternary complex thenoyltrifluoroacetone fluorescent spectra
 
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成义祥,徐端钧,徐元植.希土(Ⅲ)噻吩甲酰三氟丙酮和BipyO2/PhenNO三元配合物的合成和表征[J].无机化学学报,1997,13(2):234-236.
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