| 三(2-甲基-2-苯基丙基)锡(Ⅳ)苯氧乙酸酯的合成和晶体结构 |
| SYNTHESIS AND CRYSTAL STRUCTURE OF TRIS(2-METHYL-2-PHENYL PROPYL)TIN(Ⅳ) PHENOXYACETATE |
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| 摘要: 合成、表征了三(2-甲基-2-苯基丙基)锡苯氧乙酸酯，测定了其晶体结构。晶体属于三斜晶系，P1空间群。晶胞参数：α=1.0577(4) nm, b=2.0106(9) nm, c=1.0085(3)nm, α=95.25(3)°，β=119.07(3)°, γ=75.77(3)°, V=1.8160(1)nm3, Dc=1.22 g/cm3 |
| 关键词: 三(2-甲基-2-苯基丙基)锡苯氧乙酸酯 合成 晶体结构 |
| 基金项目: |
| Abstract: The title compound C38H46O3Sn was synthesized by the reaction of tris(2-methyl-2-phenyl propyl)tin hydroxide and phenyloxyacetic acid in benzene. The structure was characterized by elemental analysis, IR and NMR ( 1H、 13C、 119Sn) spectra. The crystal structure was determined by X-ray diffraction. The crystal belongs triclinic space group P1. The cell parameters are : α=1.0577(4) nm, b=2.0106(9) nm, c=1.0085(3) nm, α=95.25(3), β=119.07(3), γ=75.77(3), V=1.8160(1) nm3, Dc=1.22 g/cm3, Z=2, F(000)=696. The organotin compound is monomeric, with the metal atom in distorted tetrahedral coordination environment. |
| Keywords: tris(2-methyl-2-phenyl propyl)tin phenoxyacetate synthesis crystal structure |
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| 包明,贺庆林,刘宝殿,邢彦,林永华.三(2-甲基-2-苯基丙基)锡(Ⅳ)苯氧乙酸酯的合成和晶体结构[J].无机化学学报,1998,14(1):114-117. |
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