| N，N-二甲酰基二硫代氨基甲酸根金属配合物的研究 |
| STUDY ON THE TRANSITION METAL COMPLEXES OF N,N-DIFORMYLDITHIOCARBAMATE |
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| 摘要: 本文首次报道了一系列N，N-二甲酰基二硫代氨基甲酸根为配体的过渡金属配合物，对它们进行了化学分析、光谱表征和磁性质研究。研究结果表明，在配合物中，配体二硫代氨基甲酸根一般为较弱的双齿配位。 |
| 关键词: 过渡金属配合物 N，N-二甲酰基二硫代氨基甲酸根配合物 1，1-二硫代氨基配体 |
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| Abstract: A series of novel transition metal complexes of N,N-diformyldithiocarbamate, the first example of a dithiocarbamate with two N-substituted electron-withdrawing groups, have been prepared and characterized by chemical analysis as well as spectral and magnetic studies. A thorough inspection of the spectroscopic and magnetic data of these novel compounds demonstrates the weakly bidentate bonding mode of the carbodithioato ligand in the complexes. |
| Keywords: transition metal complex complexes of N,N-diformyldithiocarbanate 1,1-carbodithioato ligand |
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| 贺玲,史清芳,苟少华,方江邻,龚雁.N，N-二甲酰基二硫代氨基甲酸根金属配合物的研究[J].无机化学学报,1998,14(3):360-365. |
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