| ［La(CH2ClCOO)2(NO3)(phen)(H2O)］n的合成和晶体结构 |
| SYNTHESIS AND CRYSTAL STRUCTURE OF LANTHANIDE ［La(CH2ClCOO)2(NO3)(phen)(H2O)］n |
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| 摘要: 合成了混合阴离子配合物［La(CH2ClCOO)2(NO3)(phen)(H2O)］n。配合物经元素分析、IR、DTA-TG和UV等表征。用X射线单晶结构分析解析了标题配合物的晶体结构，三斜，空间群P1，晶胞参数为a=10.533(2)?，b=13.136(3)?，c=7.776(1)?，α=96.59(1)°，β=95.76(1)°，γ=108.42(2)°，V=1003.3(3)?3，Z=2,Dc=1.940 g/cm3, F(000)=572, μ(Mo Kα)=24.36 cm-1。 |
| 关键词: 混合阴离子 配合物 晶体结构 |
| 基金项目: |
| Abstract: We synthesized new mixed anion complex of lanthanide ［La(CH2ClCOO)2(NO3)(phen)(H2O)］n and characterized by elemental anlysis, IR, DTA-TG and UV. The crystal structure of the title complex was determined by X-ray single crystal diffraction method and the crystal parameters are as follows: triclinic, space group P1, a=10.533(2)?, b=13.136(3)?, c=7.776(1)?, α=96.59(1)°, β=95.76(1)°,γ=108.42(2)°, V=1003.3(3)?3, Z=2, Dc=1.940 g/cm3, F(000)=572, μ(MoKα)=24.36 cm-1. |
| Keywords: mixed anion complex crystal structure |
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| 朱龙观,谢学鹏,俞庆森.［La(CH2ClCOO)2(NO3)(phen)(H2O)］n的合成和晶体结构[J].无机化学学报,1998,14(4):418-421. |
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