| 奇异顺式双二茂铁三核镍配合物的合成、电化学和晶体结构(英文) |
| SYNTHESIS, ELECTROCHEMISTRY AND CRYSTAL STRUCTURE OF A NOVEL CIS-CONFIGURATION BIFERROCENE TRINUCLEAR NICKEL (Ⅱ) COMPLEX |
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| 摘要: 本文报道了希夫碱配体，N-(二茂铁基-1-甲基-甲叉)肼基硫代甲酸甲酯(简称为HL)的双二茂铁三核镍配合物的合成和表征。单晶X射线结构分析表明镍原子的配位构型为奇异的顺式平面正方形，两个二茂铁基团在镍原子的同一边。电化学测定表明正方形的镍配合物能有效地传递两个二铁基团间的电子转移。 |
| 关键词: 双二茂铁 电化学 晶体结构 电子转移 |
| 基金项目: |
| Abstract: The Synthesis and characterization of a novel biferrocene trinuclear nickel (Ⅱ) complex with Schiff base ligand, S-methyl-N(ferrocenyl-1-methyl-methylidene) dithiocarbazate (hereafter abbreviate as HL), are described, X-ray diffraction studies established that the coordinated geometry of Ni(Ⅱ) is close to square planar and in novel cis-configuration with two ferrocene moieties in the same side. Electrochemical measurements suggest that the square planar configuration of the Ni(Ⅱ) can effectively transmit the redox effects of the ferrocene moieties. |
| Keywords: biferrocene electrochemistry crytstal structure electron transfer |
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| 刘永江,刘泽华,吴德洪.奇异顺式双二茂铁三核镍配合物的合成、电化学和晶体结构(英文)[J].无机化学学报,1998,14(4):437-444. |
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