活性氧化锰的制备及表征
PREPARATION AND CHARACTERIZATION OF ACTIVE MANGANESE OXIDES
作者单位
曹阳 南京大学化学化工学院化工系南京 210093 
丁龙福 南京大学化学化工学院化工系南京 210093 
祁欣 南京大学化学化工学院化工系南京 210093 
任伟 南京大学化学化工学院化工系南京 210093 
钱文虎 南京大学化学化工学院化工系南京 210093 
摘要: 采用不同方法制备了五种活性氧化锰,并对它们进行了苯六酚氧化实验、锰氧分析、粉末XRD分析和差热-热重分析,测定了比表面积,指出组成与结构以及比表面积是影响活性氧化锰氧化活性的主要因素,为活性氧化锰的选择与使用提供了依据。
关键词: 活性氧化锰 氧化活性 组成 结构 比表面积
基金项目: 
Abstract: Five kinds of active manganese oxides were prepared with different methods. he benzenehexol-xoidizing experiments were done to them. It appeared that different samples have different oxidizing activities. The manganese-oxygen analyes were also done. Their X-ray power diffraction spectras, specific surface areas and DTA-TGA curves were determined. All the resutls were compared with β-MnO2. This paper pointed out that composition、structurer and specific surface area are the three factors that affect the oxidizing activity of manganese oxides. It provides some theoretical and practical foundation for the selectivity and utility of active manganese oxides.
Keywords: active manganese oxide oxidizing activity composition structure specific surface area
 
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曹阳,丁龙福,祁欣,任伟,钱文虎.活性氧化锰的制备及表征[J].无机化学学报,1998,14(4):473-477.
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