低热固相合成化学
SYNTHETIC CHEMISTRY FOR SOLID STATE REACTION AT LOW-HEATING TEMPERATURES
作者单位
周益明 南京大学配位化学研究所配位化学国家重点实验室南京 210093 
忻新泉 南京大学配位化学研究所配位化学国家重点实验室南京 210093 
摘要: 本文介绍了固相化学反应,概述了高热、中热、低热固相反应在合成化学中的地位,重点阐述了低热固相反应的特征及其在无机、有机、材料化学中的应用,列举已在工业生产中使用的低热固相反应实例,阐明低热固相合成确实是工业生产中一条节能、高效、减污的理想通道。
关键词: 低热固相反应 合成化学 纳米材料 非线性光学材料 工业应用
基金项目: 
Abstract: A reasonable definition for a solid state reaction is presented. And the position in synthetic chemistry for a solid state reaction at high, moderate, low-heating temperatures is described, respectively. The characteristics and the potential applications of a solid state reaction at low-heating temperatures to synthetic chemistry, especially in the syntheses of nanocrystals and non-linear optical materials, are emphasized. Some typical examples in chemical industry are illustrated to show that the application of the solid state reaction at low-heating temperatures should be developed in the future chemical industry due to its advantages of conserving energy, achieving good yield, being absent of solvent, and producing almost no pollution.
Keywords: low-heating temperature solid state reaction synthetic chemistry nanocrystal non-linear optical materials industrial application
 
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周益明,忻新泉.低热固相合成化学[J].无机化学学报,1999,15(3):273-292.
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