| 三元混配化合物［Cu(8-Q)2(phen)］·H2O及［Cu(NCS)2(phen)2］·H2O的固相合成 |
| SYNTHESIS OF TERNARY MIXED LIGAND COMPLEX ［Cu(8-Q)2(phen)］·H2O AND ［Cu(NCS)2(phen)2］·H2O IN SOLID STATE |
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| 摘要: 用室温固相反应合成了［Cu(8-Q)2(phen)］·H2O及［Cu(NCS)2(phen)2］·H2O两个三元混配化合物。室温下［Cu(Ac)2(H2O)］与邻菲啉固体几乎不发生反应，但加入第二配体8-羟基喹啉及KSCN，反应几乎立即发生。XRD、IR谱及元素分析结果表明：第二配体的加入并不仅仅促进［Cu(Ac)2(H2 |
| 关键词: 室温固相反应 三元混配化合物 稳定性 |
| 基金项目: |
| Abstract: The ternary mixed ligand complexes［Cu(8-Q)2(phen)］·H2O and ［Cu(NCS)2(phen)2］·H2O(phen=1,10-phenanthroline, 8-HQ=8-hydroxyquinoline)has been synthesized in solid state.［Cu(Ac)2(H2O)］can almost not react with 1,10-phen at room temperature. By using 8-HQ and KSCN as a second ligand respectively, the react can be carried out immediately. According to the results of EA, XRD,IR,the second ligand not only promote the reaction of ［Cu(Ac)2(H2O)］ with phen, but also participate in the reaction to produce a ternary mixed ligand complex. The synthesis of two ternary mixed ligand complexes in solid state at room temperature has not been reported up to now. |
| Keywords: solid state reactions at room temperature ternary mixed ligand complex stability |
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| 杜江燕,周志华.三元混配化合物［Cu(8-Q)2(phen)］·H2O及［Cu(NCS)2(phen)2］·H2O的固相合成[J].无机化学学报,1999,15(6):779-784. |
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