碘·(N,N'-联吡啶)·(三苯基膦)合铜(Ⅰ)的合成和晶体结构
Synthesis and Crystal Structure of Iodo(Bipyridine N,N')(Triphenylphosphine) Copper(Ⅰ)
作者单位
金琼花 首都师范大学化学系, 北京100037 
辛秀兰 北京轻工学院应用化学系, 北京100037 
朱付江 北京轻工学院应用化学系, 北京100037 
熊明 中国地质大学X-射线分析实验室, 北京100080 
摘要: 
关键词: 铜(Ⅰ)配合物  晶体结构  三苯基膦  联吡啶
基金项目: 北京市科技新星项目资助(No.952871800)
Abstract: The title compound [CuI(PPh3)(bpy)] was synthesized and the structure was determined by X-ray diffraction. The crystal belongs to monoclinic system, and C2/C space group. The cell parameters are a=28.206(5)Å, b=9.447(2)Å, c=19.025(4)Å, β=90.51(3)°, V= 5069(2)Å3, Z=8, Dc=1.601 g·cm-3. The Cu atom is in the center of the distorted coordination tetrahedron.
Keywords: copper(Ⅰ) complex  crystal structure  bipyridine  triphenylphosphine
投稿时间:1999-03-01 修订日期:1999-04-12
摘要点击次数:  1298
全文下载次数:  1937
金琼花,辛秀兰,朱付江,熊明.碘·(N,N'-联吡啶)·(三苯基膦)合铜(Ⅰ)的合成和晶体结构[J].无机化学学报,2000,16(1):111-114.
查看全文  查看/发表评论  下载PDF阅读器
Support information: