碘·(N,N'-联吡啶)·(三苯基膦)合铜(Ⅰ)的合成和晶体结构 |
Synthesis and Crystal Structure of Iodo(Bipyridine N,N')(Triphenylphosphine) Copper(Ⅰ) |
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摘要: |
关键词: 铜(Ⅰ)配合物 晶体结构 三苯基膦 联吡啶 |
基金项目: 北京市科技新星项目资助(No.952871800) |
Abstract: The title compound [CuI(PPh3)(bpy)] was synthesized and the structure was determined by X-ray diffraction. The crystal belongs to monoclinic system, and C2/C space group. The cell parameters are a=28.206(5)Å, b=9.447(2)Å, c=19.025(4)Å, β=90.51(3)°, V= 5069(2)Å3, Z=8, Dc=1.601 g·cm-3. The Cu atom is in the center of the distorted coordination tetrahedron. |
Keywords: copper(Ⅰ) complex crystal structure bipyridine triphenylphosphine |
投稿时间:1999-03-01 修订日期:1999-04-12 |
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金琼花,辛秀兰,朱付江,熊明.碘·(N,N'-联吡啶)·(三苯基膦)合铜(Ⅰ)的合成和晶体结构[J].无机化学学报,2000,16(1):111-114. |
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