| 原子簇化合物的固相合成及其三阶非线性光学性质的研究 |
| Studies on the Solid State Synthesis and the Third Order Nonlinear Optical Properties of the Mo(W)/S/Cu(Ag) Cluster Compounds |
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| 摘要: 在戴安邦教授的指导下,我们实验室多年来在室温、近室温条件下采用固相反应法合成了一系列原子簇化合物,本文则对用此方法合成的Mo(W)/S/Cu(Ag)原子簇化合物进行了分类和总结,并探讨了固相反应合成原子簇化合物的成簇规律和成簇机理。同时本文还概括和总结了Mo(W)/S/Cu(Ag)原子簇化合物的光限制效应,三阶非线性吸收与非线性折射等光学性质,初步探讨了Mo(W)/S/Cu(Ag)原子簇化合物的结构与光学性质之间的关系。 |
| 关键词: 原子簇化合物 固相合成 非线性光学性质 |
| 基金项目: 国家自然科学基金(No.29631040) |
| Abstract: Under the guidance of professor DAI An-Bang, We use solid state reaction to synthesize a series of Mo(W)/S/Cu(Ag) cluster compound in room and near-room temperature. In this paper, the Mo(W)/S/Cu(Ag) cluster compounds synthesized through this method are classified and summarized. The regularity and the possible mechanism of the cluster formation are discussed. This paper also summarizes the optical limiting effects, the third order nonlinear absorption and refraction of Mo(W)/S/Cu(Ag) cluster compounds. The correlation between nonlinear optical properties and structural types is also discussed preliminarily. |
| Keywords: cluster compounds solid-state synthesis nonlinear optical properties |
| 投稿时间：1999-10-31 |
| 摘要点击次数: 1236 |
| 全文下载次数: 1433 |
| 张弛,金国成,忻新泉.原子簇化合物的固相合成及其三阶非线性光学性质的研究[J].无机化学学报,2000,16(2):229-240. |
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