| 一个特殊的多吡啶钴(Ⅲ)配合物(英文) |
| A Novel Polypyridyl Ligand Cobalt (Ⅲ)to Complex |
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| 摘要: 本文介绍一五胺配合物[Co(terpy)(bpy)Cl]2+,三元胺是2,2′:6′,2″三联吡啶,二元胺是2,2′-联吡啶,此配合物结构特殊在于分子中没有任何酸性氢。利用其考察非碱催化水解过程中发现,该配合物的水解速率出人意料地快。这个取代反应可能是一氧化还原过程。 |
| 关键词: 特殊配合物 结构 无酸性氢 氧化还原 |
| 基金项目: |
| Abstract: A new pentaaminechlorocobalt (Ⅲ) complex [Co(terpy) (bpy) Cl]2+ has been synthesised which is unusual in that it is devoid of any acidic protons, and in this complex, the terpy and the bpy is 2, 2': 6', 2"-terpyridine and 2, 2'-bispyridine respectively.In an attempt to demonstrate a lack of (base-catalysed) hydrolysis, it was unexpectedly reactive but the process of substitution appears to be redox driven. |
| Keywords: novel complex structure no acidic proton redox |
| 投稿时间：1999-10-15 修订日期：1999-12-01 |
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| 陶朱,W. Gregory Jackson.一个特殊的多吡啶钴(Ⅲ)配合物(英文)[J].无机化学学报,2000,16(3):485-491. |
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