壳聚糖膜固定化双水杨叉乙二胺合钴的合成与表征
Synthesis and Characterazation of Co (Ⅱ) Complex of Bis(Salicylideneethylene Diamine) Immobilized to Chitosan
作者单位
胡道道 西北大学化学系, 西安710069 
史启祯 西北大学化学系, 西安710069 
唐宗薰 西北大学化学系, 西安710069 
房喻 陕西师范大学化学系, 西安710062 
摘要: 
关键词: 壳聚糖  双水杨叉乙二胺合钴  固定化配合物
基金项目: 陕西省自然科学基金(No.98H02);南京大学配位化学国家重点实验室资助
Abstract: A cobalt complex, Co (Ⅱ) complex of his(salicylideneethylene diamine, Cosalen) immobilized to chitosan film was prepared.It was instrumentally characterized by elemental analyses, IR, UV-VIS, XPS and ESR spectroscopy.It was demonstrated that the immobilization of Cosalen was realized through the coordination of the amino group in Chitosan with the Co (Ⅱ) in the CoSalen complex.It binds molecular oxygen reversibly in the solid state through the vacant sixth coordination site.
Keywords: chitosan  Co (Ⅱ) complex of his(salicylideneethylene diamine)  immobilized complex
投稿时间:1999-09-03 修订日期:1999-12-10
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胡道道,史启祯,唐宗薰,房喻.壳聚糖膜固定化双水杨叉乙二胺合钴的合成与表征[J].无机化学学报,2000,16(3):535-539.
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