| 茂钛配合物掺杂的高活性纳米镁粉的加氢性能 |
| Hydrogenation Behavior of Highly Active Nanometric Magnesium Powders Doped with Titanocene |
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| 摘要: |
| 关键词: 纳米镁粉 茂钛配合物掺杂 蒽镁热解 加氢 |
| 基金项目: 中国科学院上海有机化学研究所金属有机化学开放实验室;辽宁省教委科研基金 |
| Abstract: Titanocene( CpTiCl3) has been found to be an efficient dopant for the hydrogenation of nanometric magnesium powders. These magnesium powders are generated by the thermal decomposition of magnesium anthracene· 3THF at 90～150℃ under vacuum. They can uptake hydrogen to form magnesium hydride even at 185℃ with a hydrogenation rate much higher than those of the undoped ones under normal pressure. The order of the hydrogenation reaction with respect to the nanometric magnesium surface area is one. |
| Keywords: nanometric magnesium powders doped with titanocene thermal decomposition of magnesium anthracene hydrogenation |
| 投稿时间：1999-09-27 修订日期：2000-01-04 |
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| 范荫恒,张双青,廖世健,徐杰,王复东.茂钛配合物掺杂的高活性纳米镁粉的加氢性能[J].无机化学学报,2000,16(4):661-664. |
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