| 氨噻肟酸稀土配合物的合成、抗氧化性及抗菌活性的研究 |
| Synthesis, Antioxidative Activity and Antibacterial Activity of Complexes of Rare Earth with Syn-2-(2'-Aminothiazolyl-)-2-Methoxyimino Acetic Acid |
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| 摘要: 合成了12种稀土氨噻肟酸(HL)固体配合物,其通式为REL3(RE=La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Er,Tm,Yb,Y).利用元素分析、红外光谱、核磁共振氢谱、摩尔电导、热分析等测试手段对配合物进行了表征,研究了NdL3、ErL3配合物在DMSO溶液中电子吸收光谱,计算了电子云伸展效应参数β,共价参数δ和键合参数b1/2,讨论了配合物的共价成键情况,并对其抗氧化及抗菌活性做了研究。 |
| 关键词: 稀土配合物 氨噻肟酸 抗氧化性 抗菌活性 |
| 基金项目: 国家科委生命科学技术发展中心资助(No.96-901-05-128);新药研究国家重点实验室基金 |
| Abstract: New twelve complexes of rare earth with syn-2-(2'-aminothiazolyl-)-2-methoxyimino acetic acid (HL) have been prepared and characterized by elemental analyses, IR, molar conductance, TG-DTA and 1H NMR spectra.These complexes have the general formula REL3(RE = La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Er, Tm, Yb, Y).IR spectra indicate that the bidentate coordination mode of carboxylate ions to rare earth (Ⅲ) ion in REL3 compounds.The electronic spectra of Nd3+ and Er3+ have been studied and the spectral parameters (β, b1/2 and δ) have been calculated and discussed.The antioxidative activity and antibacterial activity have been studied. |
| Keywords: rare earth complexes syn-2-(2'-aminothiazolyl-)-2-methoxyimino acetic acid antioxidative activity antibacterial activity |
| 投稿时间：1999-12-17 修订日期：2000-04-10 |
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| 王敏,李一志,李勤喜,王流芳.氨噻肟酸稀土配合物的合成、抗氧化性及抗菌活性的研究[J].无机化学学报,2000,16(5):710-714. |
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