| N,N′- 双(3-羧基水杨醛叉缩胺乙基)草酰胺均双核铜(Ⅱ),镍(Ⅱ)配合物合成和性能研究 |
| Synthesis and Properties on Homobinuclear Cu(Ⅱ) and Ni(Ⅱ) Complexes of N,N′-Bis(3-Carboxyl Salicyl Aminal Ethylene) Oxalamide |
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| 摘要: |
| 关键词: 3-羧基水杨醛 均双核配合物 循环伏安 |
| 基金项目: 河南省教委课题(No.1999150024). |
| Abstract: The homobinuclear complexes of Cu(Ⅱ) and Ni(Ⅱ) with N,N′-bis(3-Carboxyl salicyl aminal ethylene) oxalamide were synthesized, and characterized by elemental analysis, IRspectra, Uv-visible spectra, conductometry, thermogravimetry, and magnetic susceptibility measurement, which indicated the complexes own an oxalic amide bridge-linking structure. Room temperature magnetic moment data show that there are antiferromagnetic spin coupling through oxalic amide conjugated double bond, In DMF, the redox half wave potential of Cu(Ⅱ) binuclear complexes have been measured by cyclic voltammetry, which proves that the Cu(Ⅱ) complex has two redox waves. |
| Keywords: 3-carboxylsalicylaldehyde homobinuclear complex cyclic voltammetry |
| 投稿时间：2000-07-31 修订日期：2000-10-20 |
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| 陶偌偈,娄本勇,李谦,于丽,周绪亚.N,N′- 双(3-羧基水杨醛叉缩胺乙基)草酰胺均双核铜(Ⅱ),镍(Ⅱ)配合物合成和性能研究[J].无机化学学报,2001,17(1):129-133. |
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