| 双核铜配合物{Cu[μ-S2P(C2H5O)2](C10H8N2)}2的合成和晶体结构 |
| Synthesis and Crystal Structure of Binuclear Copper(Ⅰ) Complex {Cu[μ-S2P(C2H5O)2](C10H8N2)}2 |
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| 摘要: |
| 关键词: 二烃基二硫代磷酸酯 铜配合物 联吡啶 晶体结构 |
| 基金项目: 江苏省教育厅自然科学基金项目(No.99KJB150006) |
| Abstract: Binuclear Copper (Ⅰ) Complex {Cu[μ-S2P(C2H5O)2](C10H8N2)}2 was synthesized and characterized by elemental analysis, IRand X-ray diffraction analysis.The crystal belongs to triclinic system, space group P1 with Z = 1, cell dimentions are a = 1.0613 (5), b = 1.0723 (3), c = 0.9397 (2) um, a = 111.11 (4), β = 115.57(6), γ = 85.28(2)°, V= 0.8583(6) nm3.The structure was refined to R = 0.039 and Rw = 0.042 for 2527 reflection with Ⅰ≥3σ(Ⅰ).The complex exists as a centrosymmetric dimer with a Cu-S-P-S-Cu-S-P-Schair eight-membered ring in which Cu atoms are bridged by di-μ-S-P-Sgroups. |
| Keywords: diethyldithiophosphate copper (Ⅰ) complex 2,2'-bipyridyl crystal structure |
| 投稿时间：2000-11-27 修订日期：2001-01-18 |
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| 张文莉,沈小平,贺敏强,俞运鹏,徐正.双核铜配合物{Cu[μ-S2P(C2H5O)2](C10H8N2)}2的合成和晶体结构[J].无机化学学报,2001,17(2):285-288. |
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