| 二甲基·[4-硝基-2-(氮杂苯并-15-冠-5)-1-酚氧基]合镓(Ⅲ)配合物的晶体结构 |
| Crystal Structure of Complex Dimethylgallium-[4-nitro-2-(N-benzo-15-crown-5)-1-phenoxide] |
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| 摘要: |
| 关键词: 三甲基镓 氮杂冠醚 晶体结构 |
| 基金项目: 国家863高新技术研究项目(No.715－001－0060). |
| Abstract: The complex dimethylgallium- [4-nitro-2-(N-benzo-15-crown-5)-1-phenoxide ](C23H31N2O7Ga) has been synthesized by the method reported.The crystal X-ray diffraction analysis shows that the crystal belongs to the triclinic with space group P1, M = 517.23 and the unit cell parameters: a = 1.4501 (2), b = 1.5090(2), c = 1.3865 (6)nm, a = 105.58(1 ), β = 117.26(2), γ = 66.812(8)°, V= 2.464546nm3, Z =4, Dc = 1.39g·cm-3, u = 11.6cm-1, F(000) = 1080, R = 0.051, Rw = 0.064.The coordination number of Ga is four and the gallium atom is located in a distorted tetrahedron structure. |
| Keywords: trimethylgallium azacrown ether crystal structure |
| 投稿时间：2000-12-12 修订日期：2001-02-08 |
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| 毕武,张进琪,沈曦,田敬智,邹惠仙.二甲基·[4-硝基-2-(氮杂苯并-15-冠-5)-1-酚氧基]合镓(Ⅲ)配合物的晶体结构[J].无机化学学报,2001,17(3):431-434. |
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