| 量热法测定氯化钐与甘氨酸配合物的标准生成焓 |
| The Determination of the Calorimetry of the Standard Molar Formation Enthalpy of Coordination Compound of Samarium Chloride with Glycine |
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| 摘要: |
| 关键词: 稀土氯化物 氯化钐 甘氨酸 标准生成焓 |
| 基金项目: 国家自然科学基金资助项目(No.29773033);湖北省教委科研计划资助项目(No.99CO44). |
| Abstract: The molar dissolution enthalpy of the reactants and the products of the coordination reaction of Samarium Chloride with Glycine have been measured by isoperibol solution calorimetry, the calorimetric solvent is 2mol·L-1 HCl solution.The standard molar reaction enthalpy (298.2K) is -7.3381kJ·mol-1.From the results and other auxiliary quantities, the standard molar enthalpy of formation of the new coordination compound has been calculated to be △fHmΘ(Sm(Cly)3Cl3·3H2O, s, 298.ZK)=-3631.74kJ·mol-1. |
| Keywords: rare earth chloride samarium chloride glycine standard molar formation enthalpy |
| 投稿时间：2000-12-13 修订日期：2001-03-08 |
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| 周传佩,陈文生,刘义,章习哲,屈松生.量热法测定氯化钐与甘氨酸配合物的标准生成焓[J].无机化学学报,2001,17(3):444-448. |
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