| [Cu(HIm)2(PPh3)2](BF4)的合成与晶体结构 |
| Synthesis and Crystal Structure of [Cu(HIm)2(PPh3)2](BF4) |
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| 摘要: |
| 关键词: 铜配合物 咪唑 三苯基膦 晶体结构 |
| 基金项目: 国家自然科学基金资助项目(No.29901004);广东省自然科学基金资助项目(No.000779) |
| Abstract: A Cu(Ⅰ) complex with mix ligands [Cu(HIm)2(PPh3)2](BF4) was synthesized and characterized by elemental analysis, IRspectroscopy and X-ray diffraction crystallography. The crystal belongs to monoclinic system and P21/c space group, with cell parameters, a=1.2836(3)nm, b=1.5089(3)nm, c=2.0661(4)nm, α=90°, β=101.464(4)°,γ=90°, V=3.9219(13)nm3, Z=4 and Dc=1.374mg·m-3. The Cu(Ⅰ) is coordinated by two Patoms from triphenylphosphine and two Natoms from imidazole to form the distorted tetrahedral geometry. |
| Keywords: copper(Ⅰ)complex imidazole triphenylphosphine crystal structure |
| 投稿时间：2001-02-26 修订日期：2001-04-17 |
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| 李丹,李蓉珍,齐志宇,徐严平,冯小龙,蔡继文.[Cu(HIm)2(PPh3)2](BF4)的合成与晶体结构[J].无机化学学报,2001,17(4):593-596. |
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