| 含[Cp*MS3]-的钼(钨)/铜(银)/硫簇合物合成及结构化学的新进展 |
| Progress in the Synthesis and Structure Chemistry of Mo(W)/Cu(Ag)/S Clusters Derived with [Cp*MS3]- |
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| 摘要: 本文在研究PPh4CpMS3M=MoW配体与铜银金钯盐及其配合物反应的同时根据簇合物中所含的金属原子核数把合成的23个簇合物分成九类即MM′型MM′2型MM′3型M2M′3型M2M′6型M3M′6型M3M′7型M4M′4型M4M′8型并对各类簇合物的典型结构特征进行了总结。 |
| 关键词: [Cp*MS3]- 簇合物 合成 结构化学 |
| 基金项目: 苏州大学科研基金(No.XQ109020Q4109927). |
| Abstract: In this paper,reactions of [PPh4] [Cp*MS3](M=Mo,W)with copper (Ⅰ)or silver (Ⅰ) salts or th eir complexes were briefly summarized.On the basis of nuclearity,twe nty-three clusters obtained were cl assified into nine categorie s.Those are:MM',MM'2,MM'3,M2 M'3,M2 M'6,M3M'6,M3M'7,M4M'4 and M4M'8.The main structure feature for each type was outlined. |
| Keywords: [Cp*MS3]- cluster synthesis structure chemistry |
| 投稿时间：2001-04-23 修订日期：2001-06-25 |
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| 郎建平,徐庆锋,纪顺俊.含[Cp*MS3]-的钼(钨)/铜(银)/硫簇合物合成及结构化学的新进展[J].无机化学学报,2001,17(5):609-618. |
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