| 低价钛化合物催化合成咪唑烷的一锅合成法 |
| Low-Valent Titanium Induced One-Pot Syntheses of Imidazolidines |
|
| 摘要: 本文报道了在低价钛催化下亚胺类化合物和原甲酸三乙酯发生交叉偶联反应以适中产率制得咪唑烷类化合物并对所得各种不同取代基的咪唑烷基化合物的产率和异构体比例进行了讨论。产物的构型用核磁共振波谱进行了表征。 |
| 关键词: 低价钛化合物 还原偶联 亚胺 原甲酸三乙酯 |
| 基金项目: 国家自然科学基金;中国高校博士研究基金资助项目 |
| Abstract: Under the action of a low valent titanium reagent, substituted imidazolidines were synthesized in moderate yields via cross coupling between imines and triethyl orthoformate, and the yields of product 3 with different substituted groups as well as the corresponding isomer distributions were also discussed. Related NMR spectra were used to define the configuration of the products. |
| Keywords: low-valent titanium reductive coupling imines triethyl orthoformate |
| 投稿时间：2001-04-02 修订日期：2001-06-02 |
| 摘要点击次数: 1597 |
| 全文下载次数: 1615 |
| 王少仲,席尚忠,王晓岩,黄伟,陈伟兴.低价钛化合物催化合成咪唑烷的一锅合成法[J].无机化学学报,2001,17(5):704-708. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
