几个新的席夫碱合铜(Ⅱ)配合物的合成及性质研究
Synthesis and Character of New Mixed-Ligand Complexes of Copper(Ⅱ) with Schiff-base
作者单位
唐婷 杭州医学高等专科学校中心实验室, 杭州310013 
龚钰秋 浙江大学化学系 杭州310028 
摘要: 
关键词: 铜配合物  席夫碱  合成  生物活性
基金项目: 浙江省自然科学基金资助项目(No.298068).
Abstract: In the recent years, there are many studies on the synthesis and activity of functional complexes. On the basis of preceding work, we have synthesized eight mixed ligand complexes of Cu(Ⅱ) with Schiff base derived from β diketone, salicylaldehyde and some aminoacid. Lignads of N,N′-(benzoyl acetonyl) phenylene diamine, N,N′-(diacetonyl) phenylene diamine, salicylaldehyde semicarbazone, benzoyl acetone semicarbazone, sodium salicylaldehyde histidine, potassium salicylaldehyde tyrosine, potassium benzoyl acetonyl histidine and potassium diacetonyl tyrosine are used respectively. Those have been characterized by elemental analyses, molar conductances, infrared spectra, UV spectra and TG-DTA analysis. Astudy preliminarily on the structures and characters for these compounds have been carried out in this article, and their bioactivity of restraining function to escherichia coli has also been discussed. According to all the data, the formulas of [Cu(C16H14N2)Cl2],[Cu(C11H12N2)Cl2],[Cu(C8H9O2N3)Cl2],[Cu(C12H16O2N6)]Cl2,[Cu(C13H11O3N3)(H2O)]· 3H2O,[Cu(C16H13O4N)(H2O)]· 2H2O,[Cu(C20H23O7N3)], [Cu(C15H21O7N3)] are estimated.
Keywords: copper complex  Schiff-base  synthesis  bioactivity
投稿时间:2001-03-05 修订日期:2001-06-19
摘要点击次数:  1561
全文下载次数:  2377
唐婷,龚钰秋.几个新的席夫碱合铜(Ⅱ)配合物的合成及性质研究[J].无机化学学报,2001,17(5):745-750.
查看全文  查看/发表评论  下载PDF阅读器
Support information: