| [Co(2,3-tri)(amp)Cl][ZnCl4]体系中部分几何经式异构体的结构测定 |
| Assignment of Some Geometrical mer-Isomers of[Co(2,3-tri)(amp)Cl][ZnCl4] |
|
| 摘要: 利用单晶X-射线衍射分析了[Co(2,3-tri)(amp)Cl][ZnCl4](2,3-tri=N-(2-Aminoethvl)-1,3-propanediamine;amp=2-(Aminomethyl)pyridine)体系中的一异构体(m3-[Co(2,3-tri)(amp)Cl][ZnCl4]·2.5H2O)结构,用二维核磁共振DQCOSY和NOESY技术联合解析了另两个异构体(m2-[Co(2,3-tri)(amp)C1][Zn |
| 关键词: Co(Ⅲ)配合物 经式异构体 单晶X-衍射分析 二维核磁共振技术 |
| 基金项目: 贵州省自然科学基金资助项目;贵州大学科学技术基金资助项目(No.0603;No.003) |
| Abstract: Some geometrical meridian isomers of[Co(2,3-tri)(amp)Cl][ZnCl4](2,3-tir=N-(2-Aminoethyl)-1,3-propanediamine;amp =2-(Aminomethyl)pyridine)have been assigned.The crystal structure of one isomer(m3-[Co (2,3-tri)(amp)Cl][ZnCl4]·2.5H2O)which is racemic complex with a centrally symmetric s pace group has been analyzed by X-ray diffraction determina-tion.The structures of the m2-[Co (2,3-tri)(amp)Cl][ZnCl4] and m4-[Co(2,3-tri)(amp)Cl][ZnCl4] in DMSO-d6 have been pinpointed by using 2D NMR techniques,such as DQCOSY and NOESY.They have been proven to be the meridian isomers. |
| Keywords: Cobalt(Ⅲ)complexesmeridian isomers X-ray di ffraction determination 2D NMR techniques |
| 投稿时间：2001-05-08 修订日期：2001-06-18 |
| 摘要点击次数: 1078 |
| 全文下载次数: 1725 |
| 祝黔江,陶朱,周忠远,周向葛.[Co(2,3-tri)(amp)Cl][ZnCl4]体系中部分几何经式异构体的结构测定[J].无机化学学报,2001,17(6):811-818. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
