二氰基二硫纶·联吡啶过渡金属配合物的电子吸收光谱和荧光光谱 |
Electronic Absorption Spectra and F luorescence Spectra of Transition Metal Complexes with Dicyanodithio lene and Bipyridine |
|
摘要: 本文得到二氰基二硫纶·联吡啶过渡金属配合物[M(mnt)(bpy)](M=Mn(Ⅱ)、Fe(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ);mnt=二氰基二硫纶;bpy=联吡啶)在室温下不同溶剂中的电子吸收光谱和荧光发射光谱及固态荧光光谱,讨论了该类配合物的电子吸收光谱和荧光光谱与中心金属离子及溶剂性质间的关系. |
关键词: 二氰基二硫纶 过渡金属配合物 电子吸收光谱 荧光光谱 |
基金项目: 国家自然科学基金资助课题(NO,29771025) |
Abstract: The electronic absorption spectra a nd fluorescence spectra of the title compound[M(mnt )(bpy)](M=Mn(Ⅱ)、Co(Ⅱ)、Fe(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)、Zn(Ⅱ);mnt =dicyanodithiolene;bpy =bipyridine)have been obtained in the solid and in various solevents at room temperatu re,and the relationships between the two kind spectra and the metal ions and the solvents were discu ssed,respectively. |
Keywords: discyanodithiolene tran sition metal complex electronic abs orption spectrum fluorescence spectrum |
投稿时间:2001-06-27 修订日期:2001-07-20 |
摘要点击次数: 1117 |
全文下载次数: 1358 |
王守兴,柏冬,彭正合,秦子斌.二氰基二硫纶·联吡啶过渡金属配合物的电子吸收光谱和荧光光谱[J].无机化学学报,2001,17(6):878-882. |
查看全文 查看/发表评论 下载PDF阅读器 |
Support information: |
|
|
|