酰基吡唑啉酮缩邻苯二胺希土配合物的合成、表征及生物活性
Synthesis,Characterization and Bi oactivity of Rare Earth Complexes with Furoylpyrazolone-o-Phenylenediamine
作者单位
李锦州 哈尔滨师范大学化学系, 哈尔滨150080 
于文锦 哈尔滨师范大学化学系, 哈尔滨150080 
蒋礼 哈尔滨师范大学化学系, 哈尔滨150080 
摘要: 
关键词: 酰基吡唑啉酮  双席夫碱  希土配合物  生物活性
基金项目: 黑龙江省自然科学基金资助项目(No.B9803)
Abstract: Eleven novel rare earth complexes[RE(HPMαFP)2Pen(NO3)2]NO3((HPMαFP)2 Pen:N,N’ -bis[(1-phenyl-3-methyl-5-oxo-4-pyrazolinyl )α-furylmethylidyne]-o-phenylenediimine;RE =La,Pr,Nd,Sm,Eu,Tb,Dy,Ho,Er,Yb,Y)have been synthesized.They were characterized by IR,UV-visible,1H NMR,13C NMR,fluorescence,elemental analysis and molar conductance.The resu lts show that the bis-Schiff base ligand is quadridentate and the rare earth i ons are eight-coordinated in the complexes.The antibacterial ex periment indicated that they have hi gh antibacterial activities against S.aureus,B.subtillis,E.coli,E.carotovora and C.flaccumfaciens.
Keywords: acylpyrazolone  bis-schiff base  rare earth complex  bioactivity
投稿时间:2001-04-28 修订日期:2001-06-28
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李锦州,于文锦,蒋礼.酰基吡唑啉酮缩邻苯二胺希土配合物的合成、表征及生物活性[J].无机化学学报,2001,17(6):888-892.
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