| 三氯化锑和二氧杂环己烷配合物[SbCl3·{(CH2)4O2}1.5]的合成与晶体结构 |
| Synthesis and Crystal Structure of t he Complex of Antimony Trichloride and Dioxane |
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| 摘要: |
| 关键词: 三氯化锑和二氧杂环己烷配合物 合成 晶体结构 |
| 基金项目: 国家自然科学基金资助项目(No.29771011) |
| Abstract: New solid complex of the antimony trichloride and dioxane was obtained th rough a reaction of the dioxane and the absolute methanol solution of the antimony trichloride.The formula of the complex is[SbCl3·{(CH2)4O2}1.5].The crystal structure of the complex belongs to cubic system,space group I-43d,a=17.1417(5)Å,Z =16.The trivalent antimony ion n ot only bonds directly to three chlorine anions,but also is coordinated by three oxygen atoms of th e dioxane molecules.Two oxygen atoms in a dioxane molecule will coordinate to different antimony ions,respectively. |
| Keywords: dioxane complex of antimo ny trichloride synthesis crystal structure |
| 投稿时间：2001-05-08 修订日期：2001-08-12 |
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| 臧祥生,陈娅如,栾绍嵘,钟国清,郭应臣.三氯化锑和二氧杂环己烷配合物[SbCl3·{(CH2)4O2}1.5]的合成与晶体结构[J].无机化学学报,2001,17(6):901-904. |
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