| 一维链状配位聚合物[Co(imbz)2(H2O)2]n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构 |
| Synthesis and Crystal Structure of a New One-Dimensional Chain Coordination Polymer[Co(imbz)2(H2O)2]n[imbz =4'-(Imidazol-1-ylmethyl)benzoate Anion] |
|
| 摘要: |
| 关键词: 4′-(1-咪唑基亚甲基)苯甲酸根 晶体结构 钴配合物 配位聚合物 |
| 基金项目: 国家自然科学基金资助项目(No.29971015) |
| Abstract: A new coordination polyme[Co (imbz)2(H2O)2]n[imbz =4'-(imidazol-1-ylmethyl)benzoate anion]was synthesized and characterized by x-ray crystallography.The title complex crystallizes in monoclinic,space group P21/c,a=10.910(2),b=8.8720(18),c=11.252(2)Å,β=92.20(3)°,V=1088.3(4)Å3,Z =2,Dc=1.518g·cm-3,μ=0.836cm-1,F(000)=514,R=0.0679,wR=0.1710.Each Co(Ⅱ)atom has a distorted octahedral coordination geometry and is six-coord-inated by two water molecules and fou rimbz ligands.Each imbz ligand connects two Co(Ⅱ) to gen-erate an infinite 1Dtwisted chain structure. |
| Keywords: 4'-(imidazol-1-ylmethyl )benzoate crystal structure cobalt complex coordination polymer |
| 投稿时间：2001-06-18 修订日期：2001-09-20 |
| 摘要点击次数: 1215 |
| 全文下载次数: 1331 |
| 邹志红,李东风,樊键,孙为银.一维链状配位聚合物[Co(imbz)2(H2O)2]n[imbz=4′-(1-咪唑基亚甲基)苯甲酸根]的合成及晶体结构[J].无机化学学报,2001,17(6):908-910. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
