| 间苯二甲酸连接的氢键导致的二维锌配位聚合物的合成及晶体结构 |
| A H-bond Induced Zinc 2D Coordinatio n Polymer Linked by 1,3-Benzenebicarboxylate |
|
| 摘要: |
| 关键词: 锌配合物 氢键 晶体结构 二维配位聚合物 |
| 基金项目: 国家自然科学基金资助项目(No.29871016) |
| Abstract: A H-bond induced two-dimensional in finite coordination polymer[Zn(1,3-BDC)(Im)2]n·2nCH3OH(1,3-BDC =1,3-benzenedicarboxylate,Im =imidazole)was synthesized and crystallo-graphically determined by X-ray dif fraction.The crystal structure belongs to monoclinic system with space group C2/c.a=23.1836(2),b=10.1905(1),c=17.0118(2)Å,β=115.099°,V=3639.58(6)Å3,D=1.499g·cm-3,Z =8,F000=1688,μ=1.384mm-1,R1=0.0715,wR2=0.1645.Each Zn(Ⅱ)ion is four-coordinated with a geome try of distorted tetrahedron.Each 1,3-BDC acts as a bridge to bond two neighboring zinc ions,leading to an infinite o ne-dimensional chainlike coordination polymer.Each chain wa s linked by hydrogen bonds with its neighbors to form a two-dimensional net. |
| Keywords: zinc complex hydrogen bond crystal structure two-dimensional coordination polymer |
| 投稿时间：2001-06-28 修订日期：2001-09-10 |
| 摘要点击次数: 1491 |
| 全文下载次数: 2003 |
| 李彬,孙跃飞,苟少华,姚景才,Suchada Chantrapromma,Hoong-Kun Fun.间苯二甲酸连接的氢键导致的二维锌配位聚合物的合成及晶体结构[J].无机化学学报,2001,17(6):917-920. |
| 查看全文 查看/发表评论 下载PDF阅读器 |
| Support information: |
|
|
|
|
|
|
