| Cu(Ⅱ)-牛磺酸缩水杨醛席夫碱配合物的合成及晶体结构 |
| Synthesis and Crystal Structure of [Cu(TSSB)(phen)]·1.5H2O |
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| 摘要: |
| 关键词: 铜配合物 牛磺酸缩水杨醛席夫碱 晶体结构 |
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| Abstract: The title complex was synthesized by reaction of taurine salicylic schiff base(TSSB), O-phenanthroline(phen) and cupric acetate in water-ethanol solution. The crystal structure was determined by X-ray diffraction method and the chemical formula weight of the complex is 498.00. And the crystal structure belongs to orthorhombic system with space group Pbcn and cell parameters: a=31.072(4)?, b=12.8909(18)?, c=10.3478(14)?; V=4144.7(10)?3,Z=8,Dc=1.596Mg·m-3,μ=1.197mm-1 and F(000)=2048. The compound is an one-dimensional chain complex of infinite length connecting with hydrogen bonds. The Cu(Ⅱ) was coordinated by two oxygen atoms and three nitrogen while the O atoms of Ac- groups did not coordinate. At the same time the Cu(Ⅱ)formed a distorted tragonal cone. Besides the capacities of coordination to Cu(Ⅱ) of atoms were discussed. |
| Keywords: copper complex taurine-salicylic schiff base crystal structure |
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| 全文下载次数: 1901 |
| 张淑华,蒋毅民.Cu(Ⅱ)-牛磺酸缩水杨醛席夫碱配合物的合成及晶体结构[J].无机化学学报,2002,18(5):497-500. |
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