| 具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究(英文) |
| Synthesis, Structure and Third-Order Nonlinear Optical Properties of a Planar Nickel Complex with Rigid Quadridentate Schiff Base Derived from S-benzyl Dithiocarbazate |
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| 摘要: |
| 关键词: 镍 平面结构 晶体结构 三阶非线性光学 |
| 基金项目: |
| Abstract: A planar metal complex NiL, H2L=acenaphthenequinone bis(S-benzyldithiocarbazate), 1, has been prepared via the template effect of nickel ion. Crystal structure of 1 was determined by X-ray diffraction analysis and shows the planar coordination configuration around the central nickel atom. Z-scan measurements show that 1 is a tran-sition metal complex exhibiting high third-order nonlinear optical effect. |
| Keywords: nickel planar structure crystal structure third-order nonlinear optics |
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| 周建豪,王玉晓,陈学太,宋瑛林,翁林红,游效曾.具有平面结构的四齿肼基硫代甲酸苄酯席夫碱镍配合物的合成,晶体结构和三阶非线性光学性质研究(英文)[J].无机化学学报,2002,18(5):533-536. |
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