| [Cu(Hsal)2(py)2]n晶体结构和二维堆积网络 |
| Crystal Structure and 2-D Stacking Network of [Cu(Hsal)2(py)2]n |
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| 摘要: |
| 关键词: 吡啶 水杨酸 晶体结构 芳环堆积 网络 |
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| Abstract: The title complex, [Cu(Hsal)2(py)2], was synthesized by layered-solution technique and structurally char-acterized by single-crystal X-ray. The copper atom has a square pyramidal geometry and the coordination number is five. The molecular structure is linear one-dimensional network. There is a stacking effect between pyridine ligands of neighbouring 1-D chains and the molecular structure is extended into two-dimensional stacking network. Two salicylates in the complex have a position of crab pincers-like, in which one salicylate is unidentate and another coordinates through the carboxylate group and phenyl group unidentately. |
| Keywords: pyridine salicylic acid crystal structure stacking effect of aromatic ring network |
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| 朱龙观,蔡国强,Susumu Kitagawa,Ho-Chol Chang.[Cu(Hsal)2(py)2]n晶体结构和二维堆积网络[J].无机化学学报,2002,18(9):911-914. |
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