| ZrWO4F2的前驱物法合成和表征 |
| The Precursor Route Synthesis and Characteristic of ZrWO4F2 |
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| 摘要: |
| 关键词: 锆钨氟氧化合物 ZrWO4F2 前驱物法合成 |
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| Abstract: Zirconium tungsten oxyfluoride, ZrWO4F2, was firstly synthesized with the precursor route. The composition of the compound was determined by combining the results of ICP and XPS. The indexed powder X-ray diffraction pattern of this compound indicates that it is a pure phase, orthorhombic crystal system, space group D22=P2122 and a=15.32(2)?,b=13.877(7)?,c=8.42(2)?.Combining the results of the DTA-TGA curves from room temperature to 700℃ and XRD patterns in different temperatures the mechanism was revealed during the solid precursor (1) been heated to 700℃. The zirconium tungsten oxyfluoride was considered to be a metastable com-pound. The ascertaining of annealing time and temperature is the key of handling. |
| Keywords: zirconium tungsten oxyfluoride ZrWO4F2 precursor route synthesis |
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| 吴燕,赵新华,马辉.ZrWO4F2的前驱物法合成和表征[J].无机化学学报,2002,18(12):1245-1249. |
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