| 芳香二磺酸的配位化学研究化合物[Ni(cyclam)(1，5nds)]·1/3H2O (1)和[Co(cyclam)(H2O)2](1，5nds)·2H2O (2)的合成与结构(英文) |
| Coordination Chemistry of Arenedisulfonate Syntheses and Crystal Structures of [Ni(cyclam)(1，5nds)]·1/3H2O (1) and [Co(cyclam)(H2O)2](1，5nds)·2H2O (2) |
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| 摘要: 合成了两个二价的过渡金属磺酸化合物，并通过X-射线衍射单晶结构分析进行结构表征。化合物[Ni(cyclam)(1，5nds)]·1/3H2O (1)以P2(1)/c空间群结晶，晶胞参数为a=8.583(5)，b=10.533(6)，c=12.946(7)?，β=92.433(9)°。 [Ni(cyclam)]2+与两个磺酸基团形成弱配位，从而构筑了一维的配聚物。[Ni(cycla |
| 关键词: 镍(Ⅱ) 钴(Ⅱ) 配位化学 1，5-萘二磺酸根离子 氢键 |
| 基金项目: |
| Abstract: Two novel divalent transition metal disulfonates were synthesized and characterized by X-ray single crystal diffraction. [Ni(cyclam)(1，5nds)]·1/3H2O (1) crystallized in space group P2(1)/c with unit cell parameters a=8.583(5)， b=10.533(6)， c=12.946(7)?， and β=92.433(9)°. The Ni2+ center is coordinated by the cyclam ligand and two sulfonate groups. The interactions between [Ni(cyclam)]2+ and the sulfonates are further enhanced by multiple hydrogen bonds of type O2S-O…H-N. [Co(cyclam)(H2O)2](1，5nds)·2H2O (2) crys-tallized in space group P1 with unit cell parameters a=8.738(5)， b=9.324(5)， c=10.118(5)?， α=81.382(8)， β=64.868(8)， and γ= 62.999(8)°. The sulfonate groups do not have any direct contact with the Co2+ center， instead， they form second sphere coordination with Ni2+ via hydrogen bonds and extend the structure into a 3-D network. CCDC： 194341， 194342. |
| Keywords: nickel(Ⅱ) cobalt(Ⅱ) coordination chemistry 1,5-naphthalenedisulfoante anion hydrogen bond |
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| 蔡继文,陈彩虹,周金森.芳香二磺酸的配位化学研究化合物[Ni(cyclam)(1，5nds)]·1/3H2O (1)和[Co(cyclam)(H2O)2](1，5nds)·2H2O (2)的合成与结构(英文)[J].无机化学学报,2003,19(1):81-85. |
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