| 配合物Cu(C14H10N2O2)(C5H5N)的合成和晶体结构 |
| Synthesis and Crystal Structure of Complex Cu(C14H10N2O2)(C5H5N) |
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| 摘要: |
| 关键词: Schiff碱 酰腙 铜(Ⅱ)配合物 晶体结构 |
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| Abstract: The novel copper(Ⅱ) complex with salicylaldehyde benzoylhydrazone and pyridine ligands， Cu(C14H10N2O2)(C5H5N)， has been synthesized and characterized by elemental analysis， IR and thermal analysis. The crystal structure of the title complex has been determined by single crystal X-ray diffraction techniques. The crystal belongs to monoclinic with space group P21/c. The cell parameters are： a=1.6362(9)nm， b=1.7140(9)nm， c=1.2255(7)nm， β=105.168(9)°， V=3.317(3)nm3， Z=8， Dc=1.525g·cm-3， μ(MoKα)=1.334mm-1， F(000)=1560. The structure was refined to final R1=0.0376， wR2=0.0909. The copper(Ⅱ) ion lies in a dis-torted square-planar environment composed of two oxygen atoms， one nitrogen atom of tridentate acyhydrazone Schiff base ligand and one nitrogen atom of the pyridine ligand. CCDC： 193111. |
| Keywords: schiff base acyhydrazone copper(Ⅱ) complex crystal structure |
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| 卢文贯,冯小龙,刘宏文,王少玲.配合物Cu(C14H10N2O2)(C5H5N)的合成和晶体结构[J].无机化学学报,2003,19(2):206-210. |
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