| 超分子三维氢键网络：{[Cu(phen)3](SO4)(H3PCA)2(8H2O)}的晶体结构 |
| 3D Supramolecular Hydrogen Bonding Network：Crystal Structure of {[Cu(phen)3](SO4)(H3PCA)2(8H2O)} |
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| 摘要: |
| 关键词: 铜 二维网络 三维网络 超分子 氢键 |
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| Abstract: A new complex， {[Cu(phen)3](SO4)(H3PCA)2(8H2O)}， was synthesized and structurally characterized by single-crystal X-ray analysis. The complex is composed of copper cations， sulfate anions， 1，10-phenanthroline， protocatechuic acid and lattice water molecules. The structure of H3PCA， SO42- and waters comprises packing of anionic three-dimensional network by hydrogen bonds with cavities. The complex can be considered as a model of host/guest supramolecule. The three-dimensional hydrogen-bonding network is the host species. The Cu(phen)32+ cations， guest species， occupied the cavities of the host. And the results demonstrate that the form of protocatechuic acid at pH< 1 should be free ligand. CCDC： 191733. |
| Keywords: copper 2-D network 3-D network supramolecule hydrogen bonding |
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| 何洪银,朱龙观.超分子三维氢键网络：{[Cu(phen)3](SO4)(H3PCA)2(8H2O)}的晶体结构[J].无机化学学报,2003,19(3):317-320. |
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