| 氯化四硫脲合钯配合物Pd[(NH2)2CS]4Cl2的晶体结构(英文) |
| The Crystal Structure of Palladium(Ⅱ)tetra(thiourea) Chloride Complex： Pd[(NH2)2CS]4Cl2 |
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| 关键词: 晶体结构 钯配合物 硫脲配体 |
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| Abstract: The title compound， Pd[(NH2)2CS]4Cl2， has been synthesized and structurally characterized. It crystallizes in orthorhombic， Pna2(1) space group ， with Mr=481.79(C4H16Cl2N8PdS4)， a=12.943(3)， b=8.283(2)， c=15.148(3)?， V=1623.9(6)?3， Z=4. The Pd(Ⅱ) ion has an square-planar geometry， and is coordinated by four S atom donors from four thiourea molecules. The two Cl- anions found in the apical position balance the charge. In the solid state， the title compound forms three dimensional network structures through hydrogen bonds. The inter-molecular hydrogen bonds connect the {Pd[(NH2)2CS]4}2+ and chloride ion to contribute to the stability of the structure. CCDC： 193379. |
| Keywords: crystal structure palladium complex thiourea ligand |
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| 建方方,肖海连,孙萍萍.氯化四硫脲合钯配合物Pd[(NH2)2CS]4Cl2的晶体结构(英文)[J].无机化学学报,2003,19(4):401-404. |
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