| 高氯酸二水邻菲咯啉合铜配合物的合成和晶体结构(英文) |
| Synthesis and Crystal Structure of Cu(phen)(H2O)2·ClO4(phen=phenanthroline) |
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| 摘要: |
| 关键词: 铜(Ⅰ)配合物 邻菲咯啉配体 平面正方形几何 氢键网络 分子空穴 |
| 基金项目: |
| Abstract: Crystal structure of the title compound， Cu(phen)(H2O)2·ClO4(phen=1，10-phenanthroline)， was deter-mined by X-ray crystallography. It crystallizes in the monoclinic system， space group C2/c with lattice parameters a=1.49071(4)nm， b=1.38594(4)nm， c=0.70292(1)nm， β=108.509(1)° and Z=4; The Cu(Ⅰ) ion is chelated by a phen ligand and two aqua ligands in cis arrangement and assumes a C2 symmetric square-planar geometry with the CuN2O2 core. Eight Cu(phen)(H2O)2·ClO4 molecules are interconnected by strong hydrogen bonds between coordinated water molecules and uncoordinated perchlorate anions to form a molecular scale cavities along c axis. The bond distances of Cu-N and Cu-O are 0.2003(4)nm and 0.1973(3)nm， respectively. CCDC： 197600. |
| Keywords: copper(Ⅰ) complexes phenanthroline-N1,N10 ligands square-planar geometry hydrogen bond networks molecular scale cavity |
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| 建方方,刘光晔,郝青丽,汪信.高氯酸二水邻菲咯啉合铜配合物的合成和晶体结构(英文)[J].无机化学学报,2003,19(4):419-422. |
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