| 二(三苯基膦)水杨酸铜(Ⅰ)乙醇溶剂配合物的晶体结构 |
| Crystal Structure of Bis(triphenylphosphine) Copper (Ⅰ) hydroxylbenzoate Ethanol Solvate: [(PPh3)2Cu(O2CPhOH)]·CH3CH2OH |
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| 摘要: |
| 关键词: 三苯基膦配体 晶体结构 Cu(Ⅰ)配合物 三角形 氢键 |
| 基金项目: 山东省自然科学基金资助项目(No.Y2002B06);山东省教育厅重点项目(No.J01C05)资助 |
| Abstract: The crystal and molecular structure of [(PPh3)2Cu(O2CPhOH)]·CH3CH2OH has been determined by X-ray crystallography. It crystallizes in the monoclinic system, space group P21/c, with Mr=771.26 (C45H41CuO4P2), a=0.96413(19)nm, b=1.5780(3)nm, c=2.5426(5)nm, β=100.27(3)°, V=3.8065(13)nm3, The title compound consists of discrete copper(Ⅰ) bis(triphenylphosphine) salicylate molecules and ethanol solvate. Each Cu is coordinated to two phosphorus atoms of triphenylphosphine ligands and one of carboxylate oxygens in a trigonal planar geometry. In the solid, the intramolecular hydrogen bond and extensive intermolecular interaction connecting (PPh3)2Cu(O2CPhOH) molecules and ethanol solvate form hydrogen bonds network which stabilize the crystal structure. |
| Keywords: triphenylphosphine ligand crystal structure copper(Ⅰ) complex trigonal geometry hydrogen bond |
| 投稿时间：2003-03-18 修订日期：2003-05-16 |
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| 建方方,肖海连,孙萍萍.二(三苯基膦)水杨酸铜(Ⅰ)乙醇溶剂配合物的晶体结构[J].无机化学学报,2003,19(8):869-872. |
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