| 自旋交叉配合物[Fe(ttd)2(NCS)2]·H2O的合成和磁性研究 |
| The Synthesis and Magnetic Study of Spin Crossover Complex [Fe(ttd)2(NCS)2]·H2O |
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| 摘要: |
| 关键词: 分子材料 自旋交叉 磁化率 配体ttd |
| 基金项目: |
| Abstract: The ligand ttd(ttd=1,4,8,9-Tetraaza-triphenylene-2,3-dicarbonitrile) and a novel spin crossover complex [Fe(ttd)2(NCS)2]·H2O were synthesized, and characterized by elemental analysis, IR, MS, and UV-vis spec-troscopy. The temperature dependence of magnetic susceptibility shows that there are a little break between 150～190K and an unusual step transition with a 50K width between 190～240K. Compared with the other complexes with the resemble structure, it can be found that the influence of ligand is very notable. |
| Keywords: molecule material spin crossover magnetic susceptibilities ligand ttd |
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| 陶建清,余 智,邵 挺,王天维.自旋交叉配合物[Fe(ttd)2(NCS)2]·H2O的合成和磁性研究[J].无机化学学报,2003,19(9):1011-1014. |
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